DR. HARDEO SINGH YADAV
Professor
Synthesis of inorganic & bio-inorganic complexes, coordination chemistry of oxocations, macrocyclic complexes, amavadin chemistry, green chemistry synthesis and catalysis, peroxidase activities in green vegetables / fruits, thallium chemistry in MRI and clean water technology.
e-mail: hardeoy[AT]yahoo(dot)co(dot)in,
Phone(EPBX/Office): 0360-2257401-8 extn. 6207
- Areas of Research
- Professional Background
- Honors and Awards
- Educational Details
- Administrative Background
- Sponsored Research Projects
- Memberships in Professional bodies
- Teaching Engagements
- Projects and Thesis Supervised/ Currently Supervising
- Ph. D. Students Supervised
- Special Lectures Delivered
- Publications
- To design and synthesise novel macrocyclic ligands and to study their coordination behaviour towards oxocations such as UO2(VI), VO(IV) , ZrO(IV) and MoO2(VI).
- To study the axial sites control by Peripheral substituents in superstructured dibenzotetraaza[14]annulene Ni(II) complexes.
- Chemical synthesis of Amavadin, which is a natural product, biosynthesised in mushrooms of genus Amanita, and is a 1:2 complex of Vanadium(IV) with (S,S)-2,2-(hydroxyimino)dipropionic acid, [V(S,S-HIDPA)2].
- Synthesis of meso- and optically active R,R- and S,S- forms of the ligand (N-hydroxyiminodipropionic acid) and to study its coordination behaviour towards Molybdenum and Uranium.
- To explore the catalytic activity of selenium based compounds within the green chemistry synthetic requirements. The model reaction was oxidation of 2-methyl-1,4-dimethoxynaphthalene to 2-methyl-1,4-naphthoquinone ( Menadione or Vit. K3 ).
- Peroxidase source exploration in green fruits and vegetables.
- Tl(I)/ Tl(III) Chemistry in MRI.
| FROM | TO | DESIGNATION | ORGANISATION | ||
|---|---|---|---|---|---|
| September 01, 2001 | Continuing | Professor | NERIST, Nirjuli, Arunachal Pradesh, India | ||
| May 28, 2000 | Aug 31, 2001 | Associate Professor | NERIST, Nirjuli, Arunachal Pradesh, India | ||
| Nov 20, 1998 | May 27, 2000 | Reader | D.D.U. Gorakhpur University, Gorakhpur,India | ||
| Sept 01, 1993 | Nov 19, 1998 | Associate Professor | NERIST, Nirjuli, Arunachal Pradesh, India | ||
| July 01, 1987 | Aug 31, 1993 | Assistant Professor | NERIST, Nirjuli , Arunachal Pradesh, India | ||
| Nov 19, 1985 | June 30, 1986 | Assistant Professor |
|
| Award | Institute | Year |
|---|---|---|
| INSA-PAS exchange Programme |
Institute of Chemistry with Prof Julita Eilmes, Jagiellonian University, Karasia-3, 30-060, Kracow, Poland |
Nov. 12, 1990 to Feb 10, 1991 |
| INSA-PAS exchange Programme |
Visited research lab of Prof. Jacek Mlochowski, Institute of organic and physical chemistry, Technical University of Wroclaw, 30-370, Wroclaw, Poland |
February, 1991 |
|
Nehru Centenary British Fellowship |
Department of Chemistry with Prof. David Garner, University of Manchester, Manchester, M13 9 PL, U. K. |
Oct 20, 1992 to Oct 20 1993 |
|
Nehru Centenary British Fellowship |
Institute for Anorganische Chemie, Universitat Stuttgart, Stutgart, Germany |
September 1993 |
| INSA-PAS exchange Programme |
Institute of organic chemistry, biochemistry and biotechnology, Wroclaw University of Technology, Wyb. St. Wyspianskiego 27, 50-370, Wroclaw, Poland |
Dec. 2003 to March 2004 |
| INSA-HAS exchange Programme |
Prof. Joo Ference, Homogeneous Catalysis Research group, Hungarian Academy of Science and Prof. Imre Toth, Department of Inorganic and Analytical Chemistry, Debrecen University, Hungary |
Oct-Dec. 2012 |
| Degree | Subject | University | Year |
|---|---|---|---|
| High School | Hindi,English,Biology, Science, Mathematics | UP Board | 1973 |
| Intermediate | Hindi, Engl., Biology, Chemistry, Physics | UP Board | 1975 |
| B.Sc. | Zoology, Botany, Chemistry | University of Gorakhpur | 1978 |
| M.Sc. | CHEMISTRY | University of Gorakhpur | 1981 |
| Ph.D. | CHEMISTRY | University of Gorakhpur | 1986 |
| From | To | Designation | Organisation |
|---|---|---|---|
| 19.04.2016 | 26.03.2017 | Director in-charge | NERIST, Nirjuli, Arunachal Pradesh, India |
| 1987 | 1989 | Warden , Boys Hostel | NERIST, Nirjuli, Arunachal Pradesh, India |
| 1989 | Coordinator , Recreational and Creative Activities of NERIST | NERIST, Nirjuli, Arunachal Pradesh, India | |
| 1992 | Coordinator Academic Affairs of NERIST | NERIST, Nirjuli, Arunachal Pradesh, India | |
| 1994 | Coordinator Central Research Facility | NERIST, Nirjuli, Arunachal Pradesh, India | |
| 1996 | 1990 | Chairman Central Library Committee | NERIST,Nirjuli, Arunachal Pradesh, India |
| 1996 | 1992 | Chairman Hostel Management Council and Chief Warden of all NERIST Students Hostels including Girls Hostel | NERIST, Nirjuli, Arunachal Pradesh, India |
| 1996 | 1995 | Head , Department of Chemistry | NERIST, Nirjuli, Arunachal Pradesh, India |
| 1998 | 1998 | Director's nominee as Chairman , VMC , K V NERIST | NERIST, Nirjuli, Arunachal Pradesh, India |
| 2001 | 2000 | Director's nominee as Chairman , VMC , K V NERIST | NERIST, Nirjuli, Arunachal Pradesh, India |
| 2002 | 2006 | Chairman ( 2nd Term ), Hostel Management Council and Chief Warden of all NERIST students Hostels including Girls Hostel | NERIST, Nirjuli, Arunachal Pradesh, India |
| 2001 | 2006 | Dean (Students Affairs ) | NERIST, Nirjuli, Arunachal Pradesh, India |
| 2004 | 2008 | Dean ( Students Affairs ) | NERIST, Nirjuli, Arunachal Pradesh, India |
| 2008 | 2012 | member of Dean's committee to administer the Institute constituted by the Chairman ( BOM ) | NERIST, Nirjuli, Arunachal Pradesh, India |
| 2012 | 2015 | Dean (Administration) | NERIST, Nirjuli, Arunachal Pradesh, India |
| 2006 | 2009 | Member of Board of UG Studies | Rajiv Gandhi University (under Govt. of India )Rono Hills , Itanagar(A.P) |
| Topic | Funding Agency | Year |
|---|---|---|
| Completed independently Studies on Oxovanadium(IV) Complexes | CSIR | |
| Studies on Vanadium uptake in Mashrooms | CSIR | |
| Completed with collaboration | ||
| Studies on Peripherally Substituted Macrocyles | Polish Academy of Science | 1989-1990 |
| Amavadin Chemistry and its Molybdenum Analogues | British Council | 1992-1993 |
| Studies on Selenium based one electron Mediators | Polish Academy of Science | 2004 |
| Studies on Thallium(I) & (III) Chemistry in MRI | Hungarian Academy of Science | 2012 |
- Life Member of Indian Society of Technical Education
- Member of Editorial board of Int. Journal of Advanced Chemistry, Science Publishing Corporation, Germany
| Title | Course Code | Module | Semester |
|---|---|---|---|
| CHEMISTRY-I | CY-1101 | Base | Ist |
| CHEMISTRY-II | CY-1201 | Base | IInd |
| Comprehensive Chemistry | CY-4301 | Degree | Ist |
| INORGANIC CHEMISTRY-I | CY-7101 | MS | Ist |
| INORGANIC CHEMISTRY-I | CY-7151 | MS | Ist |
| INORGANIC CHEMISTRY-II | CY-7201 | MS | IInd |
| INORGANIC CHEMISTRY-II | CY-7251 | MS | IInd |
| Title of Project | Names of Students |
|---|---|
| SRF, CSIR | Mr. V.S. Vasantha |
| DST Inspire fellow | Mr. Rajiv Khatioda |
| Topic | Scholar Name | Status of Ph. D. | Registration Year |
|---|---|---|---|
| In Collaboration: “Studies on DioxoMolybdenum(VI) Complexes wuth Synthetic Tetraaza Macrocyclic Ligand” | Dr. D.P. Rao | Completed | 2001 |
| “Synthesis and Characterization of Oxovanadium(IV) Complexes with Synthetic Macrocyclic Ligands” | Dr. Sanjay Singh | Completed | 2001 |
| “Studies on Oxovanadium(IV) Complexes with Ligands having Nitrogen and Oxygen/Sulfur Donor Atoms” | Dr. A.K. Yadav | Completed | 2001 |
| “Studies on Oxovanadium(IV) Complexes of Synthetic Macrocyclic Ligands with Oxygen and Nitrogen Donor Atoms” | Dr. S.N. Thakur | Completed | 2002 |
| Independent supervision: | |||
| “Synthesis and Characterization of Oxovanadium(VI) complexes with ligands having oxygen and Nitrogen Donor atoms” | Dr. Probin Bora | Completed | 2008 |
| “Studies on Oxovanadium(IV) Complexes with Synthesized Ligands having Oxygen, Nitrogen or Sulfur Donor Atoms” | Dr. Vijai Singh | Completed | 2009 |
| Title | Place | Date |
|---|---|---|
| 1.“Relevance of Biogas Technology for Socio- Economic Development of Arunachal Pradesh” | NERIST, Nirjuli,(A.P.) | April 7-9, 1990 |
| “The Molybdneum Analogues – A Novel Dimension to Amavadin Chemistry” | DDU Gorakhpur University,Gorakhpur(U.P.) | Sept. 26-28, 1997 |
| “ Modern Trends in Green Chemistry – Synthesis of Menadione ( Vitamin-K3 ) | Department of Organic Chemistry, Biochemistry and Biotechnology, Technical University Wroclaw, Poland | 1 March, 2004 |
| “ Synthesis of Bio-organic Ligands and Their Coordination to Molybdenum” | Department of Organic Chemistry, Biochemistry and Biotechnology, Technical University Wroclaw, Poland | 1 March, 2004 |
| “ Amavadin Chemistry in Amanita Muscaria and Future of its Synthetic Molybdenum Analogues” | Department of Chemistry, Chaiduar College Gohpur, Assam | 21-22 January, 2005 |
| “ Green Chemistry Methodology in Synthesis of Menadione” | Department of Chemistry, Chaiduar College Gohpur, Assam | 21-22 January, 2005 |
| “ One Electron Mediators in Oxidative Transformation of Organic Molecules within Green Chemistry Domain” | Department of Chemistry, Chaiduar College Gohpur, Assam | 5 – 6 October, 2007 |
| “The role of promoters in oxidative transformations of alkoxyarenes within green chemistry domain” | Department of Chemistry, Szeged University, Szeged, Hungary | Nov. 22, 2012 |
| “Synthetic routes for K - group vitamins and their possible roles in cancer therapy” | Department of Inorganic and Analytical Chemistry, University of Debrecen, Hungary | Dec. 7, 2012 |
| “Recent Trends in Tribology and its Application in Industrial Development” | Deptt. of Mechanical Engg., NERIST, Nirjuli (A.P.) | April, 10 – 14, 2013 |
| “ Advances in Welding Technology” | Deptt. of Mechanical Engg., NERIST, Nirjuli (A.P.) | May 10-11, 2013 |
| “ Ergonomics and Safety in Product Design” | Department of Agricultural Engineering, NERIST, Nirjuli (A.P.) | May 14,2013 |
| “Green Methods in Organic Transformation” | RKGEC Philkuwa, Gaziabad, New Delhi | May17, 2013 |
| “Polymer Expansion and its Future Challenges” | RKGEC Philkuwa, Gaziabad, New Delhi | May17, 2013 |
- A review article on :Applications of ligninolytic enzymes to pollutants, wastewater, dyes, soil, coal, paper and polymers. Meera Yadav and H. S.Yadav Environ. Chem. Lett., DOI 10.1007/s10311-015-0516-4, 2015.
- Synthesis and Spectral Studies of Oxovanadium(IV) Schiff Base Complexes Derived from 1,1'-Oxalyldiimidazole and Aromatic Amines. A. K. Yadava, Hardeo S. Yadav , R. Saxena and Devendra Pratap Rao Eur. Chem. Bull., 4 (7),356 – 359, 2015.
- New Insights into the Chemistry of Oxovanadium(IV) Schiff Base Complexes with Nitrogen Donor.Ashok Kumar Yadava, Hardeo Singh Yadav and Devendra Pratap Rao Journal of Science, 5(11),1086 – 1090, 2015.
- Oxovanadium (IV) Complexes with Tetraaza macrocyclic Ligands derived by Condensation of 1,2-diacetylbenzene with o-phenylenediamine, Vijay Singh, Probin Bora, H.S. Yadav, Der. Pharma. Chimica, Vol.7, 11, 2015.
- Oxovanadium (IV) Complexes with Ligands derived by Condensation of 1,2-diacetylbenzene with 2-aminobenzamide, Vijay Singh, Probin Bora, H.S. Yadav, Acta. Metallomica, Romania, MEEMB, 2014, TOME XI(II) No.2, 73-86.
- Cis-Dioxomolybdenum(VI)Complexes with Symmetrical Tetradentate Sciff Bases and their Antibacterial Activity. Devendra P. Rao, Hardeo S.Yadav and Anita Srivastava Biointerface Res. Appl. Chem., 4 (1), 678 – 684, 2014.
- New Insights into the Chemistry of Oxovanadium(IV) Complexes with N4 Coordinating Ligands. Ashok Kumar Yadava, Hardeo Singh Yadav, Umashanker Yadav and Devendra P. Rao ISRN Inorganic Chemistry, Volume 2013, ID 871640.
- Synthesis and Spectral Characterization of Some Novel Macrocyclic Complexes of Oxovanadium(IV) with 1,1'-Oxalyldiimidazole. Ashok Kumar Yadava, Hardeo Singh Yadav and Devendra Pratap Rao Eur. Chem. Bull., 2 (5), 255–258, 2013.
- Synthesis and Characterization of Tetradentate Schiff Base Oxovanadium(IV) Complexes. Probin Bora* and Hardeo S. Yadav Lativian J. of Chemistry,in Press ( 2013 ).
- In-situ Synthesis of Oxovanadium(IV) Complexes with Ligands Derived by Condensation of Benzil with Amino Acids. Probin Bora* and Hardeo S. Yadav Iranian Journal of Science & Technology, 37 ( 3 ), 2013 .
- New Insights into the Chemistry of Oxovanadium(IV) Complexes with Tetradentate Macrocyclic Ligands. Sanjay Singh,Hardeo S. Yadav, Ashok K. Yadava and Devendra P. Rao Biointerface Res. Appl. Chem., 3( 1 ), 484 – 490, 2012.
- Oxovanadium(IV) complexes with Schiff base : Synthesis, characterization and antifungal studies. PROBIN BORA* AND HARDEO S. YADAV Journal of Chemistry and Chemical Sciences, Vol.2, 116-123, 2012.
- Synthesis, Characterization and Antifungal Studies of Oxovanadium(IV) Complexes with Tetradentate Schiff Base Ligands. PROBIN BORA* AND HARDEO S. YADAV International Journal of chemical Sciences, 10 ( 4 ), 1969 - 1976, 2012.
- Synthesis and Characterization of Oxovanadium(IV) complexes having Diacetyl as precursor molecule. Probin Bora* and Hardeo S. Yadav International Journal of ChemTech research,4 (4),1428 – 1432, 2012.
- Synthesis of oxovanadium(IV) complexes with tetraaza coordinating ligands SANJAY SINGH, HARDEO S. YADAV, ASHOK KUMAR YADAVA, DEVENDRA PRATAP RAO E-Journal of Chemistry, revised , August, 2012.
- Synthesis and Spectroscopic Studies on Macrocyclic Complexes of Dioxomolybdenum(VI) with Furil as Precursor. D. P. Rao, H. S. Yadav, A. K. Yadava, S. Singh and U. S. Yadav E-Journal of Chemistry, 9 (2), 497-503, 2012.
- Synthesis, Structure and Characterization of Novel Square Pyramidal VO(IV) Complexes with O/N Donor Ligands. K. Yadav, H. S. Yadav, U. S. Yadav and D. P. Rao J. Turkish Chem. Soc. , Accepted , 2012( doi: 10.3906/kim-1201-54 ).
- Synthesis and Characterisation of cis-Dioxomolybdenum(VI) Complexes having Furil as Precursor Molecule. D. P. Rao, H. S. Yadav, A. K. Yadava, S. Singh and U. S. Yadav J. Serb. Chem. Soc. ( 2011 ) , doi : 10.2298/JSC 111110020R.
- Synthesis and Characterization of oxovanadium(IV) Macrocyclic Complexes with Ligands Derived by Condensation of Furil with 1,4-Diaminobenzene or 3,4-Diaminopyridine and Their Reactions with β - Diketones.. Sanjay Singh, H. S. Yadav, A. K. Yadava and D. P. Rao Int. J. ChemTech Res., 3 ( 4 ),1863-1869,2011.
- Synthesis and Characterization of oxovanadium(IV) Complexes with Tetradentate Schiff base Ligands Having Thenil as Precursor Molecule. Sanjay Singh, D. P. Rao, A. K. Yadava and H. S. Yadav Current Research in Chemistry, DOI: 10.3923/crc.2011.
- Luffa aegyptiaca (gourd) fruit juice as a source of peroxidase. Rama Shanker Singh Yadav, Hardeo Singh Yadav and Kamalesh Singh Yadav Enzyme Research , USA, Volume 2011, Article ID 319105.
- In-situ Preparation of Macrocyclic Complexes of Dioxomolybdenum(VI) Involving a Heterocyclic Precursor. D.P. Rao, H. S. Yadav, A. K. Yadav , Sanjay Singh and U. S. Yadav J. Coord. Chem, Vol. 64 , No. 2 , 293 - 299 , 2011.
- Template Synthesis and Characterization of Oxovanadium(IV) Complexes with Tetraaza Macrocyclic Ligands and Their Activity on Potato Virus X. S. N. Thakur, K. S.Yadav, N. P. Singh and H. S. Yadav J. Iran. Chem. Soc., Vol. 5, No. 2, 328 - 335, 2008.
- t-Butyl Hydroperoxide Oxidative Dealkylation of Hydroquinone Ethers to 1,4- Quinones. Halina Wojtowicz, Jacek Mlochowski and Ludwik Syper and Hardeo S. Yadav, Synthetic Communications,USA, vol. 36, no. 14 , 2006.
- t-Butyl Hydroperoxide Oxidation of 1,4-Dimethoxyarenes Catalysed with Selenium Compounds. Halina Wojtowicz, Hardeo S.Yadav, Jacek Mlochowski and Ludwik Syper, Annal of Polish Chemical society, vol. 3, 56 – 59 , 2004.
- The Molybdenum Analogue of Amavadin, Hardeo S. Yadav, Elain M. Armstrong, Roy L. Beddoes, David Collison and C. David Garner J.CHEM. SOC., CHEM. COMMUN., U.K. ,605, 1994.
- Synthesis and Spectroscopic Studies of Oxovanadium(IV) Complexes With 16- and 18-Membered Macrocyclic Ligands. H.S. Yadav, POLYHEDRON, 12 (3), 313, 1993.
- Template Synthesis of Oxovanadium(IV) Complexes with Tetradentate 16- Membered N6 Macrocyclic Ligands. H.S. Yadav, Asian J. Chem., 5(2) 330, 1993.
- Template Synthesis of Oxozirconium(IV) Complexes with Tetraaza 16-and 18- Membered Macrocyclic Ligands. H.S. Yadav,Asian J. Chem., 5(2), 335, 1993.
- Template Synthesis of Oxovanadium(IV) Complexes of Tetraaza 16- and 18-Membered Macrocyclic Ligands. H.S. Yadav,Bull. Soc. Chim. France, 127, 641, 1990.
- Dioxouranium(VI) Complexes of Terephathalic Acid Dihydrazide and their Reactions with β-Diketones. H.D.S. Yadav, S.K. Sengupta and S.C. Tripathi, Synth. React. Inorg. Met.-Org. Chem., 5, 1990.
- Oxovanadium(IV) Complexes of Pentadenatate 16-Membered Macrocyclic Ligands. H.D.S. Yadav, S.K. Sengupta and S.C. Tripathi, Bull. Soc. Chim. France, 1,29, 1988.
- Oxozirconium(IV) and Oxovanadium(IV) Complexes of Terephthalic Acid Dihydrazide and Their Reactions with β-Diketones. H.D.S. Yadav, S.K. Sengupta and S.C. Tripathi, Synth. React. Inorg. Met.-Org. Chem., USA, 17(1), 115, 1987.
- Synthesis and Spectroscopic Studies on Dioxouranium(VI),Oxovanadium(IV) and Oxozirconium(IV) Complexes with Tetradentate Macrocyclic Ligands. H.D.S. Yadav, S.K. Sengupta and S.C. Tripathi, Inorg. Chim. Acta, 1-6, 1987.
- Template Synthesis of Oxoziroconium(IV) Macrocyclic Complexes Derived from 2,6-Diacetylpyridine and β-Diketones. H.D.S. Yadav, S.K. Sengupta and S.C. Tripathi, Acta. Chimica, Hungary, 124(2), 1987.
- Dioxouranium(VI) Complexes of Macrocyclic Ligands Derived from 2,6-Diacetylpyridine-bis-(Thiosemicarbazones). H.D.S. Yadav, S.K. Sengupta and S.C. Tripathi, Bull. Soc. Chim. France, 5,716, 1986.
- Oxovanadium(IV) complexes of Macrocyclic Ligands Derived from 2,6-Diacetylpyridine. H.D.S. Yadav, S.K. Sengupta and S.C. Tripathi, Bull. Soc. Chim. France, 1180, 1985.
- Dioxouranium(VI) Complexes of Terdenatate 16-Membered Macrocyclic Ligands. H.D.S. Yadav, S.K. Sengupta and S.C. Tripathi. Acta. Chimica, Hungray, 119 (4), 333, 1985.
- Template Synthesis of Zirconium(IV) Macrocyclic Complexes. H.D.S. Yadav, S.K. Sengupta and S.T. Tripathi, Synth. React. Inorg. Met.-Org. Chem., USA,14, 993, 1984.